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Open image in new window Fig. Seeds treated with Suzhou Zhongchi nano device. Seeds treated with Qiangdi nano Seeds treated with prochloraz. Seeds treated with fresh water control The other experiment results also demonstrated that the growth and development of crops could be promoted by seed soaking and paddy field irrigation with nano device-treated water. The increased extent of rice biomass was 5. Rice root was increased by 5. The increased biomass of maize was The total absorption nitrogen, phosphorus, and potassium NPK of plant was increased, in which phosphorus absorption was particularly evident. The absorbed total phosphorus in rice was increased by 6. However, the nitrogen and potassium percentage contents of plants between each treatment group either did not change significantly or only reduced slightly. Only phosphorus percentage content was increased, the P2O5 contents of rice plants in each treatment group were enhanced by 0.

For example, there can be a transition in the conformation of PEDOT chains from the compressed coil form to the expanded coil form Fig. As a result of the structural reorganization, charge carriers are expected to be transported more rapidly in the expanded coil or linear conformation 20 , improving the conductivity and hole carrier mobility. Our results clearly revealed the multiple roles of DOH and informed that the blending of mild basic DOH concurrently tunes the energy level alignment and surface texture, enhances the electrical conductivity and hole mobility, yields adequate optical transparency and improves PV performances.

Furthermore, the device fabricated with DOH exhibited improved air and thermal stability. However, non-covalent hydrogen bonding can occur between the partially positive charged hydrogen atoms in the DOH and the partially negative charged oxygen in the SO3H groups of PSS Fig. Thus, PEDOT chains can transform from a coiled conformation to an expanded-coil or a linear conformation Ouyang et al.

Full size image Fourier-transform infrared FTIR spectroscopy is a useful tool for investigating the structural changes due to covalent or non-covalent interactions between the two molecules through the functional groups present in them.

The synergistic aspects of the expanded coil conformation and the interchain hopping can contribute to effective charge hopping to eventually result in improved conductivity 13 , Figure 2 C reveal the existence of two types of S2p signals. The higher binding energy peak at As shown in Fig. It was found that further incorporation of DOH beyond 1. The WF was determined according to the point of intersection of the tangent line cutoff of the curve on the x-axis, where the y-coordinate was zero.

The efficient hole extraction pathway minimizes the charge recombination and can contribute to the enhancement in the hole collection efficiency 4 , 5. A high WF cathode gold was chosen to selectively extract hole carriers and to obtain hole-only mobility in a typical P3HT based blend system Additionally, the hole mobility of the hole-only device was relatively field and temperature-independent owing to the high degree of regioregularity and the purity of the polycrystalline material P3HT 39 , The hole mobility values at room temperature were estimated as 3.

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